Detection of sunset yellow by adsorption voltammetry at glassy carbon electrode modified with chitosan

Andres Peña-Gonzalez, Olimpo García-Beltrán, Edgar Nagles

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

The simple modification of the surface of a glassy carbon electrode with chitosan (CS) allowed the development of a electroanalytical method useful for the detection and quantification of sunset yellow (SY-E110) by square wave adsorption voltammetry (SWAdV). The electrode surface was characterized with electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV). The results showed that the presence of CS on the surface of the electrode, allowed the oxidation of the SY to 1.01 V in a process controlled by adsorption. Under optimal conditions (pH 2.5, tADS 60s, EADS 0.10 V) the anodic peak current was proportional to the concentration of SY between 0.25 to 3.25 μmol L-1, with a limit of detection of 0.098 μmol L-1. The relative standard deviation (RSD) for a solution with 0.080 mmol L-1 of E110 was 2.5% for five different electrodes (n=5). The method was validated with unflavored gelatin samples spiked with known amounts of SY. The potential interferences of other synthetic dyes were studied and finally the method was tested with real samples of foods containing SY and other synthetic dyes. The results were equally acceptable compared to previous reports.

Original languageEnglish
Pages (from-to)5005-5015
Number of pages11
JournalInternational Journal of Electrochemical Science
Volume13
Issue number5
DOIs
StatePublished - 1 May 2018

Bibliographical note

Funding Information:
ACKNOWLEDGEMENTS Financial support by the Universidad de Ibagué (16-416-INT) is gratefully acknowledged.

Publisher Copyright:
© 2018 The Authors.

Keywords

  • Adsorption voltammetry
  • Chitosan
  • Glassy carbon
  • Modified electrodes
  • Sunset Yellow

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