Effect of EDTA organic coating on the spin canting behavior of maghemite nanoparticles for lead (II) adsorption

Juan A. Ramos-Guivar, Elvis O. López, Jean Marc Greneche, F. Jochen Litterst, Edson C. Passamani

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

EDTA functionalized γ-Fe2O3 nanoparticles, with controlled-sizes between 4 and 8 nm and specific surface areas up to 272 m2/g, were prepared using modified co-precipitation routes and systematically characterized using local, surface and global experimental methods. The functionalized nanoparticles behave as a magnetic trilayer-like system formed by ferrimagnetic spinel-like grains, a spin-glass-like layer as a spacer, and a cover of iron hydroxide layer with antiferromagnetic interactions. The fraction of the Fe canted spins in the spacer layer and the specific surface area are directly related to the amount of the iron hydroxide thin layer. Small (large) amounts of the iron-hydroxide layer on the nanoparticle surfaces reduce (increase) the canted Fe spin fraction, decreasing (increasing) the exchange bias effect found in the functionalized NPs. The nanoparticles with the largest specific area were applied for Pb(II) adsorption and showed a reduction of Pb(II) concentration in contaminated water to a limit less than 10 μg L−1 for an equilibrium time of 7 h. The EDTA tailored γ-Fe2O3 nanoparticles showed efficient Pb(II) adsorption, easy magnetic removal, and recycling properties, making this nanohybrid adsorbent a good potential candidate for a water cleaning process.

Original languageEnglish
Article number148021
JournalApplied Surface Science
Volume538
DOIs
StatePublished - 1 Feb 2021

Bibliographical note

Funding Information:
The authors thank Universidad Nacional Mayor de San Marcos (UNMSM), FAPES, CNPq, FAPERJ. In particular, Juan A. Ramos-Guivar acknowledges PROFIX fellowship from the Edital FAPES/CAPES TO 316/18.

Funding Information:
The authors thank Universidad Nacional Mayor de San Marcos (UNMSM), FAPES, CNPq, FAPERJ. In particular, Juan A. Ramos-Guivar acknowledges PROFIX fellowship from the Edital FAPES/CAPES TO 316/18.

Publisher Copyright:
© 2020 Elsevier B.V.

Copyright:
Copyright 2020 Elsevier B.V., All rights reserved.

Keywords

  • EDTA
  • Lead adsorption
  • Maghemite nanoparticles
  • Spin canting

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