High-resolution stimulated Raman spectroscopy and analysis of the ν2 and ν3 bands of C2H4

A. Ballandras; M. Cirtog; M. A. Loroño; M. T. Bourgeois; M. Rotger; D. Bermejo; R. Z. Martínez; J. L. Doménech; V. Boudon

doi:10.1002/jrs.4328

High-resolution stimulated Raman spectroscopy and analysis of the ν₂ and ν₃ bands of C₂H₄

A. Ballandras, M. Cirtog, M. A. Loroño, M. T. Bourgeois, M. Rotger, D. Bermejo, R. Z. Martínez, J. L. Doménech, V. Boudon

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The high-resolution stimulated Raman spectra of the ν₂ and ν₃ bands of C₂H₄ have been recorded and analyzed separately by means of the tensorial formalism developed in Dijon and Reims for X₂Y₄ asymmetric-top molecules. For the ν₂ band, a total of 191 lines were assigned and fitted. We obtained a global root mean square deviation of 1.86 × 10^-3 cm^-1. For the ν₃ band analyzed in interaction with the ν₆ infrared band, a total of 185 lines were assigned and fitted. We obtained a global root mean square deviation of 1.29 × 10^-3 cm^{- 1}. Both analyses lead to very satisfactory synthetic spectra.

Original language	English
Pages (from-to)	1033-1038
Number of pages	6
Journal	Journal of Raman Spectroscopy
Volume	44
Issue number	7
DOIs	https://doi.org/10.1002/jrs.4328
State	Published - Jul 2013
Externally published	Yes

Keywords

ethylene
formalism
global analysis
high-resolution stimulated Raman spectroscopy
modeling
tensorial

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10.1002/jrs.4328

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title = "High-resolution stimulated Raman spectroscopy and analysis of the ν2 and ν3 bands of C2H4",

abstract = "The high-resolution stimulated Raman spectra of the ν2 and ν3 bands of C2H4 have been recorded and analyzed separately by means of the tensorial formalism developed in Dijon and Reims for X2Y4 asymmetric-top molecules. For the ν2 band, a total of 191 lines were assigned and fitted. We obtained a global root mean square deviation of 1.86 × 10-3 cm-1. For the ν3 band analyzed in interaction with the ν6 infrared band, a total of 185 lines were assigned and fitted. We obtained a global root mean square deviation of 1.29 × 10-3 cm- 1. Both analyses lead to very satisfactory synthetic spectra.",

keywords = "ethylene, formalism, global analysis, high-resolution stimulated Raman spectroscopy, modeling, tensorial",

author = "A. Ballandras and M. Cirtog and Loro{\~n}o, {M. A.} and Bourgeois, {M. T.} and M. Rotger and D. Bermejo and Mart{\'i}nez, {R. Z.} and Dom{\'e}nech, {J. L.} and V. Boudon",

year = "2013",

month = jul,

doi = "10.1002/jrs.4328",

language = "Ingl{\'e}s",

volume = "44",

pages = "1033--1038",

journal = "Journal of Raman Spectroscopy",

issn = "0377-0486",

publisher = "John Wiley and Sons Ltd",

number = "7",

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TY - JOUR

T1 - High-resolution stimulated Raman spectroscopy and analysis of the ν2 and ν3 bands of C2H4

AU - Ballandras, A.

AU - Cirtog, M.

AU - Loroño, M. A.

AU - Bourgeois, M. T.

AU - Rotger, M.

AU - Bermejo, D.

AU - Martínez, R. Z.

AU - Doménech, J. L.

AU - Boudon, V.

PY - 2013/7

Y1 - 2013/7

N2 - The high-resolution stimulated Raman spectra of the ν2 and ν3 bands of C2H4 have been recorded and analyzed separately by means of the tensorial formalism developed in Dijon and Reims for X2Y4 asymmetric-top molecules. For the ν2 band, a total of 191 lines were assigned and fitted. We obtained a global root mean square deviation of 1.86 × 10-3 cm-1. For the ν3 band analyzed in interaction with the ν6 infrared band, a total of 185 lines were assigned and fitted. We obtained a global root mean square deviation of 1.29 × 10-3 cm- 1. Both analyses lead to very satisfactory synthetic spectra.

AB - The high-resolution stimulated Raman spectra of the ν2 and ν3 bands of C2H4 have been recorded and analyzed separately by means of the tensorial formalism developed in Dijon and Reims for X2Y4 asymmetric-top molecules. For the ν2 band, a total of 191 lines were assigned and fitted. We obtained a global root mean square deviation of 1.86 × 10-3 cm-1. For the ν3 band analyzed in interaction with the ν6 infrared band, a total of 185 lines were assigned and fitted. We obtained a global root mean square deviation of 1.29 × 10-3 cm- 1. Both analyses lead to very satisfactory synthetic spectra.

KW - ethylene

KW - formalism

KW - global analysis

KW - high-resolution stimulated Raman spectroscopy

KW - modeling

KW - tensorial

UR - http://www.scopus.com/inward/record.url?scp=84880047348&partnerID=8YFLogxK

U2 - 10.1002/jrs.4328

DO - 10.1002/jrs.4328

M3 - Artículo

AN - SCOPUS:84880047348

SN - 0377-0486

VL - 44

SP - 1033

EP - 1038

JO - Journal of Raman Spectroscopy

JF - Journal of Raman Spectroscopy

IS - 7

ER -

High-resolution stimulated Raman spectroscopy and analysis of the ν₂ and ν₃ bands of C₂H₄

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Keywords

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