Hydrogen-bonded chain structure of a six-coordinate 5,10,15,20-tetraphenylporphinatomanganese(III) complex

Jonathan P. Hill; Julio Santiago; Takushi Sugino; Motoo Shiro; Yo Shimizu

doi:10.1016/S0020-1693(00)00360-1

Hydrogen-bonded chain structure of a six-coordinate 5,10,15,20-tetraphenylporphinatomanganese(III) complex

Jonathan P. Hill, Julio Santiago, Takushi Sugino, Motoo Shiro, Yo Shimizu

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

In methanolic solutions, disproportionation of the TCNQ anion radical to neutral TCNQ⁰ and the dianion TCNQ^2- followed by aerobic oxidation of TCNQ^2- results in the formation of methyl-4-dicyanomethylene benzoate anion (MDCB^-). This anion coordinates to the manganese(III) atom of 5,10,15,20-tetraphenylporphinatomanganese(III) leading to the complex whose X-ray crystal structure is reported. The crystal had the monoclinic space group P2₁/n with unit cell dimensions a = 13.327(3), b = 20.236(6), c = 16.914(5) Å and β = 92.26(2)°. An important driving force behind the crystal packing is a hydrogen bonding interaction between non-identical ligands of adjacent molecules.

Original language	English
Pages (from-to)	107-111
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	315
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(00)00360-1
State	Published - 16 Apr 2001
Externally published	Yes

Bibliographical note

Funding Information:
The authors would like to thank the Agency of Industrial Science and Technology, Ministry of International Trade and Industry for the financial support under the research project ‘Harmonized Molecular Materials’. J.P.H. and J.S. acknowledge the Science and Technology Agency (STA) for providing STA fellowship.

Keywords

Hydrogen bonding interaction
Manganese(III) complexes
X-ray crystal structures

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10.1016/S0020-1693(00)00360-1

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title = "Hydrogen-bonded chain structure of a six-coordinate 5,10,15,20-tetraphenylporphinatomanganese(III) complex",

abstract = "In methanolic solutions, disproportionation of the TCNQ anion radical to neutral TCNQ0 and the dianion TCNQ2- followed by aerobic oxidation of TCNQ2- results in the formation of methyl-4-dicyanomethylene benzoate anion (MDCB-). This anion coordinates to the manganese(III) atom of 5,10,15,20-tetraphenylporphinatomanganese(III) leading to the complex whose X-ray crystal structure is reported. The crystal had the monoclinic space group P21/n with unit cell dimensions a = 13.327(3), b = 20.236(6), c = 16.914(5) {\AA} and β = 92.26(2)°. An important driving force behind the crystal packing is a hydrogen bonding interaction between non-identical ligands of adjacent molecules.",

keywords = "Hydrogen bonding interaction, Manganese(III) complexes, X-ray crystal structures",

author = "Hill, {Jonathan P.} and Julio Santiago and Takushi Sugino and Motoo Shiro and Yo Shimizu",

note = "Funding Information: The authors would like to thank the Agency of Industrial Science and Technology, Ministry of International Trade and Industry for the financial support under the research project {\textquoteleft}Harmonized Molecular Materials{\textquoteright}. J.P.H. and J.S. acknowledge the Science and Technology Agency (STA) for providing STA fellowship.",

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doi = "10.1016/S0020-1693(00)00360-1",

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T1 - Hydrogen-bonded chain structure of a six-coordinate 5,10,15,20-tetraphenylporphinatomanganese(III) complex

AU - Hill, Jonathan P.

AU - Santiago, Julio

AU - Sugino, Takushi

AU - Shiro, Motoo

AU - Shimizu, Yo

N1 - Funding Information: The authors would like to thank the Agency of Industrial Science and Technology, Ministry of International Trade and Industry for the financial support under the research project ‘Harmonized Molecular Materials’. J.P.H. and J.S. acknowledge the Science and Technology Agency (STA) for providing STA fellowship.

PY - 2001/4/16

Y1 - 2001/4/16

N2 - In methanolic solutions, disproportionation of the TCNQ anion radical to neutral TCNQ0 and the dianion TCNQ2- followed by aerobic oxidation of TCNQ2- results in the formation of methyl-4-dicyanomethylene benzoate anion (MDCB-). This anion coordinates to the manganese(III) atom of 5,10,15,20-tetraphenylporphinatomanganese(III) leading to the complex whose X-ray crystal structure is reported. The crystal had the monoclinic space group P21/n with unit cell dimensions a = 13.327(3), b = 20.236(6), c = 16.914(5) Å and β = 92.26(2)°. An important driving force behind the crystal packing is a hydrogen bonding interaction between non-identical ligands of adjacent molecules.

AB - In methanolic solutions, disproportionation of the TCNQ anion radical to neutral TCNQ0 and the dianion TCNQ2- followed by aerobic oxidation of TCNQ2- results in the formation of methyl-4-dicyanomethylene benzoate anion (MDCB-). This anion coordinates to the manganese(III) atom of 5,10,15,20-tetraphenylporphinatomanganese(III) leading to the complex whose X-ray crystal structure is reported. The crystal had the monoclinic space group P21/n with unit cell dimensions a = 13.327(3), b = 20.236(6), c = 16.914(5) Å and β = 92.26(2)°. An important driving force behind the crystal packing is a hydrogen bonding interaction between non-identical ligands of adjacent molecules.

KW - Hydrogen bonding interaction

KW - Manganese(III) complexes

KW - X-ray crystal structures

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DO - 10.1016/S0020-1693(00)00360-1

M3 - Artículo

AN - SCOPUS:0035897115

SN - 0020-1693

VL - 315

SP - 107

EP - 111

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

ER -

Hydrogen-bonded chain structure of a six-coordinate 5,10,15,20-tetraphenylporphinatomanganese(III) complex

Abstract

Bibliographical note

Keywords

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