Synthesis and characterization of silver(I) complex with mixed ligands saccharinate and 2-(2-pyridyl)bezimidazole

Mario Ceroni Galloso; Jorge Reinaldo Angulo-Cornejo; Maria Nieves Lino-Pacaheco; Claudia Cecilia Villanueva Huerta; Enzo Martín Casimiro Soriano

doi:10.15446/rev.colomb.quim.v47n2.68225.

Synthesis and characterization of silver(I) complex with mixed ligands saccharinate and 2-(2-pyridyl)bezimidazole

Translated title of the contribution: Synthesis and characterization of silver(I) complex with mixed ligands saccharinate and 2-(2-pyridyl)bezimidazole

Mario Ceroni Galloso, Jorge Reinaldo Angulo-Cornejo, Maria Nieves Lino-Pacaheco, Claudia Cecilia Villanueva Huerta, Enzo Martín Casimiro Soriano

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

A new silver coordination compound [Ag(sac)(pbi)] was synthesized by reaction of silver(I) saccharinate with 2-(2-pyridyl)benzimidazole (pbi) in 64% yield. The characterization was performed by elemental analysis, IR, UV-Visible, XPS,¹H-NMR, and¹³C-NMR spectroscopy. According to the results, silver is coordinating through three nitrogen atoms: one from saccharinate and the others from 2-(2-pyridyl)benzimidazole forming with this ligand a five-membered chelate ring.

Translated title of the contribution	Synthesis and characterization of silver(I) complex with mixed ligands saccharinate and 2-(2-pyridyl)bezimidazole
Original language	English
Pages (from-to)	73-78
Number of pages	6
Journal	Revista Colombiana de Quimica
Volume	47
Issue number	2
DOIs	https://doi.org/10.15446/rev.colomb.quim.v47n2.68225.
State	Published - 1 May 2018
Externally published	Yes

Bibliographical note

Funding Information:
The authors thank Innóvate Perú for contract N° 364-PNICP-PIBA-2014 and Dr. Lothar Hennig from Leipzig University, Germany, for the NMR spectra.

Publisher Copyright:
© 2018, Universidad Nacional de Colombia. All rights reserved.

Keywords

2-(2-pyridyl)benzimidazole
Saccharinate
Silver
XPS

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10.15446/rev.colomb.quim.v47n2.68225.

Cite this

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title = "Synthesis and characterization of silver(I) complex with mixed ligands saccharinate and 2-(2-pyridyl)bezimidazole",

abstract = "A new silver coordination compound [Ag(sac)(pbi)] was synthesized by reaction of silver(I) saccharinate with 2-(2-pyridyl)benzimidazole (pbi) in 64% yield. The characterization was performed by elemental analysis, IR, UV-Visible, XPS,1H-NMR, and13C-NMR spectroscopy. According to the results, silver is coordinating through three nitrogen atoms: one from saccharinate and the others from 2-(2-pyridyl)benzimidazole forming with this ligand a five-membered chelate ring.",

keywords = "2-(2-pyridyl)benzimidazole, Saccharinate, Silver, XPS",

author = "{Ceroni Galloso}, Mario and Angulo-Cornejo, {Jorge Reinaldo} and Lino-Pacaheco, {Maria Nieves} and {Villanueva Huerta}, {Claudia Cecilia} and {Casimiro Soriano}, {Enzo Mart{\'i}n}",

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doi = "10.15446/rev.colomb.quim.v47n2.68225.",

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T1 - Synthesis and characterization of silver(I) complex with mixed ligands saccharinate and 2-(2-pyridyl)bezimidazole

AU - Ceroni Galloso, Mario

AU - Angulo-Cornejo, Jorge Reinaldo

AU - Lino-Pacaheco, Maria Nieves

AU - Villanueva Huerta, Claudia Cecilia

AU - Casimiro Soriano, Enzo Martín

PY - 2018/5/1

Y1 - 2018/5/1

N2 - A new silver coordination compound [Ag(sac)(pbi)] was synthesized by reaction of silver(I) saccharinate with 2-(2-pyridyl)benzimidazole (pbi) in 64% yield. The characterization was performed by elemental analysis, IR, UV-Visible, XPS,1H-NMR, and13C-NMR spectroscopy. According to the results, silver is coordinating through three nitrogen atoms: one from saccharinate and the others from 2-(2-pyridyl)benzimidazole forming with this ligand a five-membered chelate ring.

AB - A new silver coordination compound [Ag(sac)(pbi)] was synthesized by reaction of silver(I) saccharinate with 2-(2-pyridyl)benzimidazole (pbi) in 64% yield. The characterization was performed by elemental analysis, IR, UV-Visible, XPS,1H-NMR, and13C-NMR spectroscopy. According to the results, silver is coordinating through three nitrogen atoms: one from saccharinate and the others from 2-(2-pyridyl)benzimidazole forming with this ligand a five-membered chelate ring.

KW - 2-(2-pyridyl)benzimidazole

KW - Saccharinate

KW - Silver

KW - XPS

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AN - SCOPUS:85050346648

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ER -

Synthesis and characterization of silver(I) complex with mixed ligands saccharinate and 2-(2-pyridyl)bezimidazole

Abstract

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Keywords

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