Synthesis and rietveld refinement of (Y<inf>1-x</inf>Pr<inf>x</inf>)Ba<inf>2</inf>Cu<inf>3</inf>O<inf>7</inf> compound

Flores S. Jesus, Bustamante D. Angel, Feijoo L. Juan, J. C. Gonzalez, Sanchez C. Dalbert, Geraldo R.C. Cernicchiario

Research output: Contribution to conferencePaper

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© 2012 Published by Elsevier B.V. Selection and/or peer-review under responsibility of the Guest Editors. A structural study of the incorporation of Pr-ion into the Y-site was realized in polycrystalline samples of (Y1-xPrx)Ba2Cu3O7 through of Rietveld analysis of X-ray diffraction patterns, bond valence method and electronic density diagrams. The crystalline structure stabilized into orthorhombic phase (Pmmm) for x=0, but the unit cell increases its symmetry by doping the Y-site and stabilizing into a tetragonal phase (P4/mmm) for x=0.5. Moreover, the structural results obtained were correlated with the magnetization measurements, where the Tc decreased from 90K (x=0.0) to 49K (x=0.3). The oxygen content in the compounds was checked by means of μ-Raman spectroscopy, observing the frequency position of O(4)-Ag phonon mode.
Original languageAmerican English
Number of pages6
StatePublished - 1 Jan 2012
EventPhysics Procedia -
Duration: 1 Jan 2012 → …


ConferencePhysics Procedia
Period1/01/12 → …


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