Harmonic force constants of boron trihalides and some mixed halides of boron

Juan Roberto Anacona, Marcos Loroño

Resultado de la investigación: Contribución a una revistaArtículorevisión exhaustiva

2 Citas (Scopus)

Resumen

A reliable set of harmonic force constants was calculated for BF3, BCl3, BBr3, BI3, BF2Cl, BF2Br, BCl2F, BCl2Br, BBr2F, and BBr2Cl using the observed vibrational frequencies of these compounds (containing 10B or 11B isotopes) and the iterative consistency method. The final force field reproduces quite satisfactorily the experimental frequencies. Some of the principal stretching force constants were found to vary systematically with the electronegativity of the halogen.

Idioma originalInglés
Páginas (desde-hasta)279-284
Número de páginas6
PublicaciónJournal of Molecular Structure: THEOCHEM
Volumen304
N.º3
DOI
EstadoPublicada - 20 feb. 1994

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