Hydrogen-bonded chain structure of a six-coordinate 5,10,15,20-tetraphenylporphinatomanganese(III) complex

Jonathan P. Hill, Julio Santiago, Takushi Sugino, Motoo Shiro, Yo Shimizu

Resultado de la investigación: Contribución a una revistaArtículorevisión exhaustiva

4 Citas (Scopus)

Resumen

In methanolic solutions, disproportionation of the TCNQ anion radical to neutral TCNQ0 and the dianion TCNQ2- followed by aerobic oxidation of TCNQ2- results in the formation of methyl-4-dicyanomethylene benzoate anion (MDCB-). This anion coordinates to the manganese(III) atom of 5,10,15,20-tetraphenylporphinatomanganese(III) leading to the complex whose X-ray crystal structure is reported. The crystal had the monoclinic space group P21/n with unit cell dimensions a = 13.327(3), b = 20.236(6), c = 16.914(5) Å and β = 92.26(2)°. An important driving force behind the crystal packing is a hydrogen bonding interaction between non-identical ligands of adjacent molecules.

Idioma originalInglés
Páginas (desde-hasta)107-111
Número de páginas5
PublicaciónInorganica Chimica Acta
Volumen315
N.º1
DOI
EstadoPublicada - 16 abr 2001

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