Mesomorphic properties of porphyrin silicon(IV) metal complexes

Takushi Sugino, Julio Santiago, Yo Shimizu, Benoî Heinrich, Daniel Guillon

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Resumen

A dihydroxo(dodecyltetraphenylporphinato)silicon (IV) and its corresponding dimethoxosilicon (IV) derivative were synthesized to examine the mesomorphic properties of the metal complexes by differential scanning calorimetry, optical microscopy, and X-ray diffraction analysis. The study of the mesomorphic behavior of the porphyrin complexes will allow a better understanding of the influence of the axial groups on the thermal behavior, which has been demonstrated for a hydroxoaluminum complex of tetraphenylporphyrin.

Idioma originalInglés
Páginas (desde-hasta)1259-1266
Número de páginas8
PublicaciónMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volumen330
DOI
EstadoPublicada - 1999
Publicado de forma externa
EventoProceedings of the 1998 17th International Liquid Crystal Conference - Strasbourg, France
Duración: 19 jul. 199824 jul. 1998

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