TY - JOUR
T1 - Preparation and characterization of the superconductor [Y 0.8Ca0.2]SrBaCu2.8(BO3) 0.2O6.4 compound
AU - Barinotto, Victor H.C.
AU - Willems, Bram L.
AU - Angel Bustamante, D.
AU - Luis De Los Santos, V.
AU - Juan Gonzalez, G.
N1 - Funding Information:
This work was undertaken at the Universidad Nacional Mayor de San Marcos and was supported by its Consejo Superior de Investigación. J.C. Gonzalez thanks Dr. X. Obradors from ICMAB Spain, for the SQUID measurement and to AECI Spain for awarding a fellowship to pursue his doctoral support.
PY - 2004/8
Y1 - 2004/8
N2 - We report the study of the [Y0.8Ca0.2]SrBaCu 2.80(BO3)0.2O6.4 compound which is a superconductor with critical temperature of 45 K. This compound was prepared by the solid state reaction method under normal conditions of pressure and temperature, replacing 0.2 of oxianion borate (BO3)3- in the copper site of [Y0.8Ca0.2]SrBaCu3O 7-δ. TC was determined by measuring the magnetic susceptibility using a SQUID detection system. The X-ray difractogram revealed a monophasic pattern, Rietveld analysis suggested an orthorhombic crystalline structure belonging to the Pmmm spatial group with a = 3.826 Å, b = 3.861 Å and c = 11.561 Å.
AB - We report the study of the [Y0.8Ca0.2]SrBaCu 2.80(BO3)0.2O6.4 compound which is a superconductor with critical temperature of 45 K. This compound was prepared by the solid state reaction method under normal conditions of pressure and temperature, replacing 0.2 of oxianion borate (BO3)3- in the copper site of [Y0.8Ca0.2]SrBaCu3O 7-δ. TC was determined by measuring the magnetic susceptibility using a SQUID detection system. The X-ray difractogram revealed a monophasic pattern, Rietveld analysis suggested an orthorhombic crystalline structure belonging to the Pmmm spatial group with a = 3.826 Å, b = 3.861 Å and c = 11.561 Å.
KW - Borate
KW - Rietveld analysis
KW - XRD
UR - http://www.scopus.com/inward/record.url?scp=4444350475&partnerID=8YFLogxK
U2 - 10.1016/j.physc.2004.02.052
DO - 10.1016/j.physc.2004.02.052
M3 - Artículo de la conferencia
AN - SCOPUS:4444350475
SN - 0921-4534
VL - 408-410
SP - 58
EP - 59
JO - Physica C: Superconductivity and its Applications
JF - Physica C: Superconductivity and its Applications
IS - 1-4
T2 - Proceedings of the International Conference on Materials
Y2 - 25 May 2003 through 30 May 2003
ER -