TY - JOUR
T1 - Synthesis and molecular structure of bis(2-benzoylimino-benzimidazolinato)copper(II)-dimethylformamide - A metal-containing guanidine derivative
AU - Beyer, Lothar
AU - Richter, Rainer
AU - Wolf, Robert
AU - Zaumseil, Jana
AU - Lino-Pacheco, Maria
AU - Angulo-Cornejo, Jorge
N1 - Funding Information:
L.B. would like to thank the Fond der Chemischen Industrie for financial support. M.L. thanks the DAAD Bonn for a grant. We thank Dr. K.H. Hallmeier for recording and discussion of the XPS spectra and Dr. L. Hennig for recording and discussion of the NMR spectra.
PY - 1999/5/1
Y1 - 1999/5/1
N2 - Bis(2-benzoylimino-benzimidazolinato)copper(II) (1) as the first neutral chelate of an acylimino-benzimidazoline contains guanidine and amide moieties directly coordinated to a metal atom. The ligands are arranged in trans position. The synthesis of cis-bis(pyridine)bis(N-benzoyl-O-ethyl-N′-m-nitrophenyl-isoureato) nickel(II) (2) is described. The molecular structures of both complexes were determined by X-ray crystal structure analysis.
AB - Bis(2-benzoylimino-benzimidazolinato)copper(II) (1) as the first neutral chelate of an acylimino-benzimidazoline contains guanidine and amide moieties directly coordinated to a metal atom. The ligands are arranged in trans position. The synthesis of cis-bis(pyridine)bis(N-benzoyl-O-ethyl-N′-m-nitrophenyl-isoureato) nickel(II) (2) is described. The molecular structures of both complexes were determined by X-ray crystal structure analysis.
KW - Acylisourea complexes
KW - Copper(II) complexes
KW - Crystal structures
KW - Guanidine derivative complexes
KW - Nickel(II) complexes
UR - http://www.scopus.com/inward/record.url?scp=0033423786&partnerID=8YFLogxK
U2 - 10.1016/S1387-7003(99)00043-X
DO - 10.1016/S1387-7003(99)00043-X
M3 - Artículo
AN - SCOPUS:0033423786
SN - 1387-7003
VL - 2
SP - 184
EP - 187
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
IS - 5
ER -